In order to elucidate the interaction of ligands to the BSA, the thermodynamic parameters ([DELTA]G, [DELTA]H and [DELTA]S) have been calculated by using van't Hoff
equation at the temperatures 298, 303 and 308 K.
Thermodynamics (Van't Hoff
) C Slope [DELTA]H [DELTA]S [DELTA]G [R.sup.2] (K) (KJ/Mol) (KJ/MolK) (KJ/Mol) KT 9.41 -2.52 48.27 0.18 -6.33 0.98 AT 7.97 -2.11 40.40 0.15 -5.8 0.94 KI 9.54 -2.58 49.30 0.18 -5.95 0.96 AI 8.07 -2.14 40.96 0.15 -5.86 0.96 Key: Coag.
Using the data shown in Table 1, we could obtain the van't Hoff
equations at different scan rates, which are given in Table 2.
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Strained hydrocarbons; beyond the van't Hoff
and Le Bel hypothesis,
's suggestion of the tetrahedral arrangement of the carbon atoms.
de Kruif, Van't Hoff
Laboratory, Debye Institute, Utrecht University, 3584CH, Utrecht, Netherlands; phone: +31 30 253 91 11; fax: +31 30 253 33 88; email: deKruif@nizo.nl.