(S)-(-)-N(trifluoroacetyl)pyrrolidine-2-carbonyl chloride (L-TPC) is one of the well-known CDAs that is readily available in chemical market and shows impressive results in chiral separation of the phenylalkylamines mainly on GCMS after derivatization reaction [8, 9, 24].
Ethyl acetate, acetic acid, methanol, 2-propanol, ammonium hydroxide, dichloromethane, 0.1 M solution of (S)-(-)-N-(trifluoroacetyl)pyrrolidine-2-carbonyl chloride (L-TPC) with an enantiomer excess (ee) of 97% (according to the supplier's specification) in methylene chloride, anhydrous sodium sulfate, and sodium phosphate were obtained from Sigma-Aldrich Chemicals (St.
Asiri, "Synthesis and biological evaluation of new N,N'-Bis(1-substituted-ethylidene)-ethane1,2-diamine and their acetyl and trifluoroacetyl
derivatives as cytotoxic and antimicrobial agents," Journal of Chemistry, vol.
Biochemical studies on the plant methanolic, hexane and aqueous extracts show the presence of the quinoline alkaloid lunacridine to be effective against tropical ulcers , antitubercular  and antibacterial activity [17,18], graveolinine, 4-methoxy-2-phenylquinoline and kokusagine for antituberculosis activity , lunacridine and its trifluoroacetyl
derivative for DNA intercalation, topoisomerase II decatenation, cytotoxicity and caspase activation activities  and Cytochrome P450 2D6 inhibitory effect .
trifluoroacetic acid is formed in the trifluoroacetyl
The so-called CF3 chemistry has been an important pillar for the site since the 1980s, when the production process for trifluoroacetyl
chloride (TFAC) was developed.
To enhance the anxiolytic activity of some azepine derivatives by the introduction of a trifluoromethyl group in the dia-, oxa- or thiazepine, trifluoroacetyl
ketene acetals 167 were reacted with o-aminothiophenol derivatives in the presence of xylene, applying a multimode microwave oven (8-12 min at 980 W).
(2006) Highly efficient synthesis of heterocyclic compounds based on reactivity of trifluoroacetyl
The 100 [micro]m polydimethylsiloxane provided the highest analytical sensitivity for the trifluoroacetyl
derivative of 9-hydroxyphenanthrene, while the 70 [micro]m Carbowax[TM]/divinylbenzene provided the next best analytical sensitivity and a simpler chromatogram with less derivatization byproducts.
Time course of 72-kilodalton heat shock protein induction and appearance of trifluoroacetyl
adducts in livers of halothane exposed rats.
 report the vibrational assignment of trifluoroacetyl
acetone using B3LYP, B3PW91, BLYP, BPW91, and G96LYP functionals.
Residues were reconstituted and derivatized with 50 [micro]L of MBTFA at 70 [degrees]C for 45 min to obtain trifluoroacetyl
derivatives of the analytes (30).