Oxidation, epoxidation and sulfoxidation
reactions catalyzed by haloperoxidases.
GSH conjugation products include TCVG, the cysteine conjugate TCVC, and the mercapturate NAcTCVC and its sulfoxidation products.
Sulfoxidation of mercapturic acids derived from tri- and tetrachloroethene by cytochromes P450 3A: a bioactivation reaction in addition to deacetylation and cysteine conjugate [beta]-lyase mediated cleavage.
Included are stereoselective oxidation and reduction methods; stereoselective additions; cyclizations; metatheses and different types of rearrangements; asymmetric transition-metal-catalyzed, organocatalyzed, and biocatalytic reactions; methods for the formation of carbon-heteroatom and heteroatom-heteroatom bonds like asymmetric hydroamination and reduction amination, carboamination and alkylative cyclization, cycloadditions with carbon-heteroatom bond formation, and stereoselective halogenations; and methods for the formation of carbon-sulfur and carbon-phosphorus bonds and asymmetric sulfoxidation
Consistent with the unsupervised PCA model, differential oxidation was observed most prominently as methionine sulfoxidation
of apoAI and apoCI.
2,3)) The genetic polymorphism in SCMC sulfoxidation
results in the subdivision of the population into three cohorts with respect to their ability to sulfoxidize the sulfur moiety of the drug (figure).
CPO catalyzes chlorination, epoxidation, hydroxylation and asymmetric sulfoxidation
reactions at the expense of [H.
The role of cytochrome p4503a1/2 in the sex-specific sulfoxidation
of the hexachlorobutadiene metabolite, N-acetyl-S-(pentachlorobutadienyl)-L-cysteine in rats.
of the soil fumigants metam, methyl isothiocyanate, and dazomet.
of the pesticide methiocarb by flavin-containing monooxygenase and cytochrome P450-dependent monooxygenases of rat liver microsomes.
Specific and enantioselective sulfoxidation
of an aryl-trifluoromethyl sulfide by rat liver cytochromes P-450.
Industrial-Scale Asymmetric Sulfoxidations
In The Synthesis Of Two Related Nk1/Nk2 Antagonists