MgN after solvation
with ethylene glycol ([Mg.sub.EG]).
The interactions occurring in different solutions can also be confirmed by the solvation
number, which is measure of structure forming or structure breaking tendency.
Peytavy, "Stability of Water-in-Crude Oil Emulsions: Role Played by the State of Solvation
of Asphaltenes and by Waxes," J.
Therefore the sonication effect should reflect the solvation
mode of ester molecules.
In this study, the responses of the porphyrin [[pi].sup.*] [left arrow] [pi] transition energies were investigated with respect to changes in the composition of binary solvent mixtures, using nickel and freebase porphyrins with several different peripheral substituents, For mixtures in which preferential solvation
is not significant, the responses of the absorption band energies were investigated with respect to functions of the solvent mixture refractive index which relate to the polarizability of the solvent environment.
The free energy of solvation
AGaq, and the corresponding pKa values have been calculated by using eq.2-5.
It is interesting to observe that the SMD solvation
model is powerful enough to allow discriminating between the values for the global descriptors in both solvents.
Synthesis, characterization, and unusual solvation
and luminescent properties of terbium amine complexes.
All of the calculations include the solvation
effect in ethanol using the polarizable continuum model (PCM) .
In the literature, column classification in SFC has been carried out by chemometric analysis based on linear solvation
energy relationships (LSER) [3,5,11,25,29].
[DELTA][G.sub.np] is the nonpolar solvation
contribution and was calculated with constants 0.0072 kcal [mol.sup.-1] [[Angstrom].sup.-2] for surface tension proportionality constant [gamma] and 0.92 kcal [mol.sup.-1] [[Angstrom].sup.-2] for the nonpolar free energy for a point solute [beta].
The first section is concerned with the forces holding together supramolecular assemblies of ions and begins with an overview of the history and methodology of ion solvation