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Moreover, Mosley et al [27] documented in the in vitro study a direct octadeceonoate cis-trans isomerization in mixed rumen bacteria, capable of converting oleic acid into trans-11 as well as other trans isomers.
adopted the [11C + 2C + 1C] synthetic strategy and synthesized the sex pheromone monomers with two different constructions by using triple-bond cis-trans hydrogenation [14].
They transform the space of gender categorization from a one-dimensional continuum into a two-dimensional space, defined by the cis-trans axis as well as the male-female axis.
The peptidlyprolyl cis-trans isomerase signature existed in the LvCypA, which is located in 48-56 sites, respectively (Figs.
Cyclophilin A is a protein exhibiting peptidyl-prolyl cis-trans isomerase activity because of which it assists in protein folding (3).
PPIases catalyze the cis-trans isomerization of proline imidic peptide bonds and regulate protein folding and maturation.
My intention in this article is to study the cis-trans isomerization and isomers formed during the thermal induction of methyl linolenate at 275[degrees]C.
It may be concluded that ppiases catalyze the peptidyl-prolyl cis-trans isomerization, the ratelimiting step of protein folding, which is essential for newly synthesized protein to get its correct functional form.
This could be explained in that the higher reaction temperature promoted cis-trans isomerization to enhance both the trans-1,4 and vinyl--1,2 units at the expense of the cis-1,4 isomer [23, 25], An increase in the reaction temperature also decreased the Mw of the Co/Nd-BR since the higher reaction temperature induced chain transfer, which led to a lower Mw with a broader MWD of the resulting BR [1, 23],
It has been observed that solvent polarity is one of such factors, which influences cis-trans isomerization reaction of merocyanines; this fact was explained by the effect of solvent polarization on the intramolecular motion [12].
The cis-trans isomerization of peptide bonds is a slow process on the NMR time scale under normal conditions at ambient temperature due to the high barrier resulting from the C-N partial double bond character.
[52] proved the activation of the cis-trans isomerase in resting cells by the addition of 3-nitrotoluene.