complex 1 has a 3D structure formed by the combination of mono and binuclear
chains, complexes 2 and 3 have identical structures with one only difference in the length of the auxiliary ligands.
The effect of oxygen and dissolved air in compound 4 was studied observing a decrease in the intensity of emission upon addition of oxygen and increase in this emission when it is substituted by nitrogen, and in the solid state, this binuclear
exhibited a slight mechanochromism in response to mechanical grinding; this behavior can be attributed to changes in the molecular arrangements.
The 1-2 and 4 binuclear
core showed a Rh-Rh bond distance in an expected range of 2.3925(6), 2.3886(5), and 2.3860(6) A, respectively (see Figures 5(a)-7(a) and Table 3) [68-70].
(29) Olefin polymerization behavior of binuclear
heteroligated Ti(IV) catalyst based on phenoxyimine ligand.
P Yan, "Synthesis of and magnetic interactions in binuclear
Cu(II)M(II) (M=Cu, Ni and Mn) complexes of macrocyclic oxamido ligands," Polyhedron, vol.
In these binuclear
Pd(II) complexes, 1,10-phenanthroline (phen) acts as capping ligand and al-bis-dtc bridges the two Pd centers.
By this reaction, and also by binding the copper binuclear
centers in a noncompetitive manner , NO can regulate cytochrome c oxidase activity and, more widely, it can tune mitochondrial respiration.
The cyclic voltammogram of the modified graphite paste electrode with CuHSA showed one redox couple with formal potential E = 0.75 V versus Ag/AgCl(sat) (KCl 1.0 mol [L.sup.-1] ; v = 20 mV [s.sup.-1]) attributed to the redox process Fe(n)[(CN).sub.6]/Fe(m) [(CN).sub.6] of the binuclear
complex formed .
As shown in Figure 6(a), the spatial distribution of Gucun residents' activities is a nonuniform distribution shaped like a binuclear
Peng, "Visible-light-induced photocatalytic hydrogen production over binuclear
RuII-bipyridyl dye-sensitized Ti[O.sub.2] without noble metal loading," Chemistry--A European Journal, vol.
13, 29 (2005) ("[T]he adversarial adjudicatory process is unequal to the task of retrofitting parents for their new roles as parents living in what will be a binuclear