benzylic


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Related to benzylic: allylic

ben·zyl·ic

(ben-zil'ik),
Relating to or containing benzyl.
References in periodicals archive ?
In addition, wide range of benzylic, aliphatic, and allylic alcohols was also studied for selective oxidation into their corresponding carbonyl compounds, which yielded complete convertibility within short reaction times under mild reaction conditions.
Comparative Catalytic Evaluation of Nano-Zr[O.sub.x] Promoted Manganese Catalysts: Kinetic Study and the Effect of Dopant on the Aerobic Oxidation of Secondary Alcohols
Yang et al., "Oxidation of benzylic compounds by gold nanowires at 1 atm [O.sub.2]," Chemical Communications, vol.
Heterogeneous metal catalysts for oxidation reactions
Silane (13) has a chlorine atom bonded to an allylic group, and silane (4) has a chloride bonded to a benzylic group.
New silane coupling agents for NR/truck tire applications
The decomposition reaction was monitored by following the benzylic protons in the (1.) H NMR spectrum.
CHEMISTRY AND CHEMICAL ENGINEERING
As a starting point, Louvain chemist Istvan Marko relied on studies in the late 1970s on the aerobic extraction of benzylic alcohols using copper-amine complexes as mediators.
Processing promises to go greener
Pincock has begun to obtain a real understanding of the factors that control the competition between homolytic and heterolytic photocleavage of benzylic substrates and is trying to apply these principles to develop synthetically useful procedures.
Chemistry at Dalhousie University
More examinations also resulted that in the case of benzylic and aromatic secondary amines such as benzylamine and N-methylaniline, the protocol was also efficient and produced the corresponding formamides in 88-90 % yields (entries 18 and 19).
New Catalytic Performance of Immobilized Sulfuric Acid on Activated Charcoal for N-formylation of Amines with Ethyl Formate
Similarly, the other ortho-coupled doublets at [delta] 7.13 (2H, H-3'' & H-5'') and [delta] 7.05 (2H, H-2'' & H-6'') along with a benzylic methylene signal at 4.77 (s, 2H, C[H.sub.2]-7'') were helpful to ascertain the substitution of 4-chlorobenzyl moiety on nitrogen atom of the targeted sulfonamide.
Synthesis, Antibacterial and Lipoxygenase Inhibition Studies of N-(Alkyl/aralkyl)-N-(2,3-dihydro-1,4-benzodioxin-6-yl)-4-methylbenzenesulfonamides/N-(Alkil/aralkil)-N-(2,3-dihidro-1,4-benzodioksin-6-il)-4-metilbenzensulfonamitlerin Sentezi ile Antibakteriyel ve Lipoksijenaz Inhibitor Ozellikleri
In the last case, the presence of benzylic positions that can be easily halogenated using BCl3 has prevented the synthesis of hexa-alkyl substituted boron subphthalocyanines even under favorable reaction conditions that include the use of DBU and DBN as promotors and higher temperatures [10].
Synergetic Enhancement of the Photocatalytic Activity of Ti[O.sub.2] with Visible Light by Sensitization Using a Novel Push-Pull Zinc Phthalocyanine
prepared plum-pudding type Pd@Ce[O.sub.2] and used it as a visible light photocatalyst for selective oxidation of benzylic alcohols to corresponding aldehydes in a process in which photogenerated electron produced superoxide radicals, thereby facilitating the oxidation [34].
Liquid-Phase Ethanol Oxidation and Gas-Phase CO Oxidation Reactions over M Doped (M = Ag, Au, Pd, and Ni) and MM' Codoped Ce[O.sub.2] Nanoparticles
Hernandez-Soriano et al., "Structural functionality, catalytic mechanism modeling and molecular allergenicity of phenylcoumaran benzylic ether reductase, an olive pollen (Ole e 12) allergen," Journal of Computer-Aided Molecular Design, vol.
In silico prediction of T and B cell epitopes of Der f 25 in Dermatophagoides farinae
Urban, "Complex amphiphilic networks derived from diamineterminated poly(ethylene glycol) and benzylic chloride-functionalized hyperbranched fluoropolymers," Journal of Polymer Science A: Polymer Chemistry, vol.
Synthesis of fluorinated amphiphilic block copolymers based on PEGMA, HEMA, and MMA via ATRP and CuAAC click chemistry
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