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Related to Rearrangement reaction: addition reaction, Beckmann rearrangement, Pericyclic reaction


A restructuring, for example, in a molecule.
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These results demonstrated that the methyl at 5-position of 3-nitrosoindolizine derivatives is very critical and important for the ring-opening and rearrangement reaction. Furthermore, the reactivity of compound 5 and 8 in acetic anhydride and acetic acid was tested.
The reason is that the main reaction is [epsilon]-caprolactam formation through a cyclic rearrangement reaction (Bockhorn et.