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transamidation

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transamidation
the process of transferring an amide group from one molecule to another.
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The distribution of the monodisperse amide segments did not broaden upon melt polymerization, suggesting that hardly any transamidation reactions took place (8).
Influence of polydispersity of crystallizable segments on the ... by Biemond, G.J.E.; Feijen, J.; Gaymans, R.J. / Polymer Engineering and Science
This could be ascribed to a diluent effect of the amorphous component, characteristic of miscible crystalline-amorphous blends (14) and/or to transamidation reactions between the blend components during the melt-mixing process (15).
Structural organization and drawability in polyamide blends by Persyn, O.; Miri, V.; Lefebvre, J.M.; Depecker, C.; Gors, C.; Stroeks, A. / Polymer Engineering and Science
Since amic acid formation is an equilibrium reaction, transamidation can occur when two PAAs or two precursors with very similar structure are combined in solution.
Characterization of Two Precursor Polyblends: Polyhydroxyamide and ... by CHANG, JIN-HAE; FARRIS, RICHARD J. / Polymer Engineering and Science
 
 
 
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