rotamer

(redirected from rotamers)

ro·ta·mer

(rō'ta-mĕr),
An isomer differing from other conformation(s) only in rotational positioning of its parts, such as synperiplanar and synclinal forms.

ro·ta·mer

(rō'tă-mĕr)
An isomer differing from other conformation(s) only in rotational positioning of its parts, such as cis- and trans- forms.
References in periodicals archive ?
4 in which the influence of the THF ring's orientation on the potential energy of the rotamers is represented.
The density for Br2' is weaker than that for Br4', likely due to different rotamers of the second ring, which would maintain the position of Br4' but reposition Br2' in multiple orientations.
Complete equilibrium geometries have been determined for both rotamers by ab initio calculations employing a variety of basis sets up to 6-311+G(2d,2p) at levels of restricted Hartree-Fock (RHF) and/or Moller Plesset (MP) to second order.
Two of these are dual-conformation peptide units; the remainder involves alternate rotamers of side chains either alone or in small clusters.
The relative energies of rotamers range between 0 to 16 kcal/mol.
Briefly, the lowest energy rotamers present a syn methylester group on an E side chain with a pseudo H-bond between the hydroxy H and the prenyl [pi] density (Fig.