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hemiacetal

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hem·i·ac·e·tal (hm-s-tl)
n.
Any of a class of compounds containing an alkyl group, especially when formed as intermediates during the preparation of acetals from aldehydes or ketones.

hemiacetal
formed by nucleophilic addition of an alcohol to the carbonyl group of an aldehyde. Most open-chain hemiacetals are not stable, but cyclic hemiacetals of the type present in aldehyde sugars such as glucose are more stable.


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This occurs through hemiacetal linkages between hydroxyl groups of cellulose/hemicellulose and aldehyde groups formed at C6 primary hydroxyl groups of cellulose by the TEMPO-mediated oxidation.
 
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