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ligand |
Also found in: Dictionary/thesaurus, Encyclopedia, Wikipedia, Hutchinson | 0.56 sec. |
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ligand /li·gand/ (li´gand) (lig´and) an organic molecule that donates the necessary electrons to form coordinate covalent bonds with metallic ions. Also, an ion or molecule that reacts to form a complex with another molecule.
ligand [lig′ənd, lī′gənd] Etymology: L, ligare, to bind 1 a molecule, ion, or group bound to the central metal atom of a chemical compound, such as the oxygen molecule in oxyhemoglobin, which is bound to the central iron atom. 2 an organic molecule attached to a specific site on a cell surface or to a tracer element. The binding is reversible in a competitive binding assay. It may be the analyte or a cross-reactant. Examples include vitamin B12, a ligand with intrinsic factor as the binding protein, and various antigens, which are ligands with antibody-binding proteins. ligand (līg n 1. a molecule, ion, or group bound to the central atom of a chemical compound, such as the oxygen molecule in hemoglobin, which is bound to the central iron atom. 2. an organic molecule attached to a specific site on a surface or to a tracer element. ligand an organic molecule that donates the necessary electrons to form coordinate covalent bonds with metallic ions. Also, an ion or part of a molecule that specifically binds to form a complex with another molecule. How to thank TFD for its existence? Tell a friend about us, add a link to this page, add the site to iGoogle, or visit webmaster's page for free fun content. |
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The presence of a bulky bidentate polar modifier at the chain end may decrease linking efficiencies, similar in effect to the presence of sterically hindered monomer units at the chain terminus (ref. 160 LEUTENEGGER U,TETRAHEDRON,vol 0048,page 2143,1992,cites= 27,5 -AZA-SEMICORRINS - A NEW CLASS OF BIDENTATE NITROGEN LIGANDS FOR ENANTIOSELECTIVE CATALYSIS In the case of MDI foams, it seems that the covalent network is of good quality even at high water/low MDI indices; however, the virtual network, consisting of the hard segments, is very weak as reflected by the high swelling and nonexistent bidentate carbonyl links (determined by FTIR). |
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