In order to elucidate the interaction of ligands to the BSA, the thermodynamic parameters ([DELTA]G, [DELTA]H and [DELTA]S) have been calculated by using
van't Hoff equation at the temperatures 298, 303 and 308 K.
Thermodynamics (
Van't Hoff) C Slope [DELTA]H [DELTA]S [DELTA]G [R.sup.2] (K) (KJ/Mol) (KJ/MolK) (KJ/Mol) KT 9.41 -2.52 48.27 0.18 -6.33 0.98 AT 7.97 -2.11 40.40 0.15 -5.8 0.94 KI 9.54 -2.58 49.30 0.18 -5.95 0.96 AI 8.07 -2.14 40.96 0.15 -5.86 0.96 Key: Coag.
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Van't Hoff, chairman of Shell UK, said: "Our Hot 40 2011 represents the very best of entrepreneurial talent in the UK.
Graham
van't Hoff, chairman of Shell UK, said: "There is a wealth of entrepreneurial talent in the UK and I hope other young entrepreneurs will be inspired by Laura to capitalise on their own ideas.
Graham
van't Hoff Chairman of Shell UK, said: "Shell Springboard offers no-strings financial awards to businesses to progress their ideas and help these technologies come to fruition."
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Strained hydrocarbons; beyond the
van't Hoff and Le Bel hypothesis,
van't Hoff's suggestion of the tetrahedral arrangement of the carbon atoms.
de Kruif,
Van't Hoff Laboratory, Debye Institute, Utrecht University, 3584CH, Utrecht, Netherlands; phone: +31 30 253 91 11; fax: +31 30 253 33 88; email: deKruif@nizo.nl.