Synthessis of 2-acetyl pyridine
pyridinium bromide (2)
When two viologen fragments were connected with a propyl linker, the molecule exhibited a higher tendency for a chelatelike complexation with chloride anions in polar DMSO/[H.sub.2]O media, where chlorides were found to be complexed through a dense hydrogen bond network [31], while the iodides were found to be driven by charge-transfer processes with the electron-deficient
pyridinium rings in the crystal lattice [31].
On the other hand, the reaction of 13 with 2 equivalents of
pyridinium p-toluenesulfonate (PPTS) [14] in 2-propanol at 50[degrees]C for 48 h afforded a mixture of compounds 1a/1b (53% yield) in a 1:1 ratio, together another compound (27%) still containing only one protective methoxymethoxy group.
FTIR spectrum of the purified product reveals the presence at about 1652 [cm.sup.-1] of the band assigned to
pyridinium group [13], besides the bands at 1601 (> C=N), 1034-1102 (Si--O--Si), 1271 (Si--[CH.sub.3]), 812 (Si--[CH.sub.3]) (Fig.
At the same time, there are several published and patented works based on the successful industrial application of Ni plating baths based on Ni sulfate (NiSO4(H2O)6), Ni chloride (NiCl2*6H2O), and Ni sulfamate (H4N2NiO6S2) salts [5].The effects of diamin [6], propargyl alcohol (PA), butynediolethoxylate (BEO), and
pyridinium sulphobetaine (PPS) additives were also investigated [7].
Pyridinium and imidazolium ionic liquids were tested, and it was observed that the same ionic liquids have extraction ability to both S- and N-compounds [1, 20, 21].
For example, an isobutane-butene alkylation catalyzed with butyl
pyridinium chloroaluminate, and co-catalyzed with t-butyl chloride, in literature has been mentioned [1].
In this work, we therefore propose an investigation of the properties of hexadecyl
pyridinium, 1-vinyl hexadecyl imidazolium, 1-vinyl octa-decyl imidazolium, dihexadecyl imidazolium, dioctadecyl imidazolium, and tributyl hexadecyl phosphonium modified montmorillonites and of their linear low density polyethylene nanocomposites.
Levels of serum and synovial fluid
pyridinium crosslinks in patients with rheumatoid arthritis.