Furthermore, as the vertical
activation energy of the equilibrated samples is not reduced irreversibly by processing, it is stated that the degree of branching is not affected by mechanical degradation.
And hot deformation apparent
activation energy of the AZ81E alloy is 166.15 kJ/mol, approximately.
The
activation energy and ash content of raw coal were determined as 41.24 kJ/mol and 35.84%, respectively.
The Arrhenius equation was used in a modified form to illustrate the relationship between the effective moisture diffusion and the ratio of the microwave output power to sample weight (m/P) instead of the temperature for calculation of the
activation energy. The modified Arrhenius equation (6) derived by Dadali et al.
After fitting is conducted over the fixed viscosity and temperature reciprocal, the
activation energy of the viscous flow of a slag component was obtained according to the slope.
The f([alpha]) function can be determined from a nonisothermal curve if
activation energy is known (Malek 1989).
Where Ea, R, Ko and T are
activation energy for the hydration process in kJ.mol-1, universal gas constant in 8.314x10-3 kJ mol-1 K-1, frequency factor or pre-exponential constant in % s-1, the soaking temperatures (K), respectively.
The
activation energy values we got for FeAc and FeAc-FD are smaller than those ones found in scientific literature for some transition metal acetates [8].
Several models [11-14] employed single
activation energy value to estimate kinetic parameters, assuming a first order of reaction, whilst other methods [5, 7, 15] made use of the distribution of
activation energy values over the entire range of pyrolysis process.
where d[alpha]/dt is the reaction speed, [s.sup.-1]; k is the speed constant; E is the
activation energy, J/mol; R is the universal gas constant, J/(mol x K); T is the temperature, K; [alpha] is the degree of transformation, %.