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chemical shift
(redirected from Chemical Shift Anisotropy)

   Also found in: Acronyms, Encyclopedia, Wikipedia 0.01 sec.
chemical shift,
(in nuclear magnetic resonance spectrometry) the position of a resonance in the substance of interest relative to the position of the resonance of a standard. Nonequivalent atoms of a molecule have different chemical shifts.


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The Magic Angle Spinning (MAS) of the samples leads to the complete averaging of the chemical shift anisotropy (CSA) and dipolar interactions: it follows that highly resolved spectra can be recorded even for powdered samples.
 
 
 
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