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autoxidation
(redirected from Allylic hydrogen)

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autoxidation /au·tox·i·da·tion/ (aw-tok″sĭ-da´shun) auto-oxidation.
au·tox·i·da·tion (ô-tks-dshn)
n.
See autooxidation.
autoxidation [aw″tok-sĭ-da´shun]
the spontaneous reaction of a compound with molecular oxygen at room temperature.
autoxidation, auto-oxidation
the spontaneous reaction of a compound with molecular oxygen at room temperature.
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As abstraction may be the dominant mechanism, there is a higher allylic hydrogen concentration in isoprene (7 vs.
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Allylic substitution can be ruled out since there are no allylic hydrogens in maleic acid.
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Pharmacological studies have demonstrated that andrographolide supports conceptual hydrogen transfer, which would be thermodynamically favoured for its allylic hydrogen on carbon C-11.
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