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acetonitrile |
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acetonitrile /ac·e·to·ni·trile/ (as″ĕ-to-ni´trīl) a colorless liquid with an etherlike odor used as an extractant, solvent, and intermediate; ingestion or inhalation yields cyanide as a metabolic product. How to thank TFD for its existence? Tell a friend about us, add a link to this page, add the site to iGoogle, or visit webmaster's page for free fun content. |
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all experiments, the reaction mixture, at the incubation times
indicated, was added to alpha-cyano-4-hydroxy cinnamic acid (CHCA) at 5
mg/mL in 50% acetonitrile, 0. " In an experiment Robson calls
"simple in the extreme," they built the molecular network by
replacing each of four roughly spherical acetonitrile groups (a carbon
atom bonded to three hydrogen atoms and one carbon-nitrogen couple),
loosely hooked to a common copper atom, with a more complex chemical
made of four rodlike molecular segments, each capable of bonding to a
copper atom. The structures of three of these solvates (with
ethylacetate, acetonitrile and methanol) were all obtained from
single-crystal data, whereas the crystal structure of the parent
compound itself has been solved from powder diffraction data using the
Monte Carlo technique [8]. |
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